A1079

The world’s copper king to build “Lithium-Ion battery Empire”

Posted by admin on February 04, 2010
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Launched largest countries in the lithium battery electric vehicle project

Following the 2009 in Suzhou, the first to produce its own lithium Sony VGP-BPS2B Sony VGP-BPS2C battery electric vehicles, it is now Henan Jinlong pushed backwards – at the end of January in the original Yang began the annual output of 2 million the lithium battery electric vehicle project

 

January 21 morning, the Golden Dragon Group Board of Directors decided to convene: Following Suzhou lithium electric car project implemented, Xinxiang Yuanyang frozen to build a production base of electric cars lithium battery production line a total investment of 150 million yuan, annual production should reach 2 million vehicles. This project will become the largest lithium battery electric vehicle project.

 

In compliance with the dragon’s plan to expand the 2011 lithium battery electric vehicle production scale, but more recently, the condition of vehicles lithium electricity market are particularly good, especially in the region Yangtze Delta, where consumers are more receptive to new things, we produce the electric car does not sell, so that future expansion of production. “Subsidiary of Golden Dragon Group in Suzhou, Lung Engineer Yeuk Yin Yong Ting said. Vostro 1500 battery Vostro 1700 battery

 

January 21 afternoon, the Golden Dragon Group is responsible for research and development of lithium-Yong Yin Huang, with the chief engineer Wang Shikui and have covered over 40 kilometers of Xinxiang Jinlong Yang freezer production base in first group, the siting study. “This infrastructure has been improved, there are workshops, as the installation of equipment is expected to decline this year, the production line is completed, we can reach an annual output of 2 million level.” Kui said Wangshi . ‘Our goal is to project fully completed by 2015 and complete presentation of strategic group in the country, reaching an annual production of 5 million in vehicle production and operation of the size and become the largest manufacturer of nation of electric bicycles. “Li Changjie said.

 

Both carmakers to power battery

Golden Dragon Group, in addition to the hippocampus, Lifan outside the power of car batteries, and Zhengzhou Nissan, Yutong has also established a link. PA3399U-2BAS PA3399U-1BRS

 

January 25, Director General of Golden Dragon Group Hebei Xue-Feng and his party arrived in Chongqing Lifan, Lifan has met the highest level. Both parties to the Golden Dragon Group, Lifan Group, has reached a preliminary plan to provide motive power batteries, even if the content is confidential, but he revealed: “has been resolved, and soon the signing of agreement is concluded. “

At the end of January, Golden Dragon has signed a cooperation agreement with the hippocampus. Companies “In the future, the hippocampus batteries power electric vehicles by us, this number is quite impressive.” Wang Shikui this cooperation was very pleased: “At the moment, and the combination of the hippocampus, but also tend to run cars for official use Test how problems are identified, to identify weaknesses, and then solve the problem, eventually toward industrialization.”

 

“For us, may provide the impetus for the hippocampus and batteries Lifan, we will develop a wide area. Wangshi Kui said. A1045 PowerBook G4 15 battery

 

Golden Dragon Group Dynamic Power Co., Ltd., Henan Li Ji Cheng, executive vice president of the introduction, in addition to, and the hippocampus, Chongqing Lifan co operation, they and the Nissan Zhengzhou Yutong and other companies have also established a cooperative relationship.

We also produce electric vehicles that

 

The production of electric cars, only the first step of the road shock Jinlong Li Changjie has a more ambitious target – vehicles produce electric current, the current prototype has been produced by the September 1, 2009, Golden Dragon Group and Taiwan’s Aerospace Industrial Development Corporation jointly, joint ventures, the annual production capacity of 300,000 batteries from cars and power projects, joint working and the battery power search electric vehicles and the development and production. The project covers an area of 2000 hectares, is located in Xinxiang National Chemistry and Physics Industrial Park in 2010, began full production in 2012 after the completion of the project can achieve annual sales revenue of 50 billion yuan. ThinkPad R50 battery ThinkPad R51 battery

 

Although Li Changjie, said an official for the electric vehicle market, but also take a few years, but in fact, Golden Dragon Group Taicang in Jiangsu Province to produce lithium-electric vehicles such as electric cars, not only the tractor, karting, passenger cars, patrol cars, as well as for residents of houses with cars, these electric vehicles are used by the own production of Golden Dragon Group lithium batteries.

 

In printing the reporter that, although many airports, stations are used in electric tractors. “These tractors are used in common lead-acid batteries, speed is only 20 kilometers per hour but the battery is not sustainable, but also pollutes the environment. We produce a range of tractor result of its lithium-even up to 80 km / h above, very appropriate for the military, airports, train stations, the use of the Liberation. People’s Army General Armament Department has many cars I’ve seen, and very interested, willing and we, them that the market is large. “Yin Yong Ting said.

According to reports, the current produced by the sample households, there are two electric vehicles: Jeep-style, style of vehicles. “We will participate in the car this fall, the Shanghai Expo, so that everyone finds fault with the issue. But the case of a production license in the state.” Huang Yin-Yong said: “Quick, come next year, the Pixia. Vostro 1320 battery Vostro 1400 battery

 

Reward for attracting Jinlong electric shock

Always show people the face of precision Golden Dragon Copper Tube Group, has opened a new door – lithium-moving vehicles. For a lithium battery lithium electric vehicles for commercial vehicles, the plan of Golden Dragon Group for their future again and again a whole new way.

 

Golden Dragon Group is the largest global manufacturer of precision copper tubes, the product nationally for over 60% market share, which represents one sixth of global market share. As an industry brass boss, Jinlong Why join the lithium industry? “Although we have brass in 2009 reached over 100 billion yuan of production value, but the benefits of the processing industry is relatively low. A new energy is different, and in 2009 the benefits of lithium batteries only about 7000 million euros, compared to the number of our copper is ah “When it comes to enter the lithium batteries, Li Changjie excited.”In the future, new energy will be our other pillar industries. 3 ~ 5 year lithium battery electric vehicles, battery power and production of electric vehicles will reach 500 billion size of the output value will be much more than copper. “Lithium battery separator material in the past of s ’support on imports, and now, independent research Golden Dragon Group and developing production of alternatives represented a certain percentage of the domestic market share and become a beneficiary of the company news-making issues. ” Cheng Ji, introduced in April 2008, Xinxiang special grant of 200 acres of city land, the chemical group and physical condition in Xinxiang Industrial Park, built in the section Xinxiang Technology Co., Ltd., is committed to lithium , G5266 HD438 battery, 3V lithium battery, new energy and related materials research and industrial. “We are now the largest manufacturer of lithium-powered batteries.

 

As Li Changjie said, support the Golden Dragon Copper Tube Group, the industry of air conditioning, power industry to a new long-range extension is that the Golden Dragon Group, separator in lithium battery acquired the intellectual property rights, access to proprietary technology for IP cases in China. Li Changjie so proud is now manufacturing batteries Golden Dragon Group power necessary to take account of the inner part of the membrane material in the battery industry lithium has a greater impact and benefits of technological development.

 

Henan Province is to build electric cars

Golden Dragon Force Group in the hair behind the electric car is the bias of policies in the province of Henan. Under the guidance of policy, many manufacturers have launched the electric car

In November 2009, our province has introduced the latest development of the electric car industry plan of action, intends to expand the Zhengzhou hybrid bus demonstration in support of Operation Xinxiang demonstration to promote trade public spaces and the operation of the 10 demonstration areas for the development of electric vehicles. To support the electric vehicle industry, our province has allocated 5,000 million dollars and has been implemented. Funds this year, the province also allocated are used to finance the development of electric vehicles, the amount of money the current plan is 100 million yuan. In addition, businesses in the province or individuals may apply for grants to buy electric cars. hp Pavilion dv8000 battery  hp Pavilion dv4 battery

 

In terms of stimulus, not only the dragon, other companies have entered the electric car R & D and production.

Electric Vehicle Engineering Institute, Henan Province, according to information provided, Zhengzhou Yutong Bus in the vehicle and fuel systems technology is relatively mature, and its research and development of pure electric buses and hybrid covering 10 ~ 12 meters more models.

Zhengzhou Nissan Automobile converted a number of cars Paladin, equipped with 336V, 100AH lithium batteries, using Hangzhou universal system power management, for the National Grid service vehicle. The near future plans to Rui Qi, Odin two electric vehicles in a taxi-type.

 

China Aviation Industry Group ZHENG Fei-electric car motors and the controller now has two core technologies, currently more than 100 vehicles produced mini-cars have been conducted over many months of testing on the road, and got the last Cab Card Administration Office of Zhengzhou eligibility.

Shaolin car has developed three types of models, the initial plan this year, production of 2000 units, and gradually developed into 5,000 units.

Electric Vehicle Program China First Tractor is in the early preparation.

 

January 24, the provincial government takes the initiative in creating the League of Henan electric vehicle industry. At the meeting, provincial director of the Office of Industry and Information Sheng Yang Tao, Zhengzhou, Henan based on four major auto manufacturers (hippocampus, Yutong, Nissan, Shaolin) to build the production base electric vehicles in the five major M8403 A1079 battery manufacturers have Xinxiang (Golden Dragon, Universal Group, the electricity of the air lithium, etc.) to build electric car production base of batteries. The eventual realization of “equipment, equipment, Henan, Henan” goal. After passing through the bottleneck techniques, ran on the Central Plains will be built in Henan are electric vehicles.

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High-security system, lithium-ion battery materials research and application

Posted by admin on January 29, 2010
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Solid reaction method of state was used with lithium, iron, phosphate salts as raw materials, raw materials grinding dry, baked at high temperatures in an inert atmosphere or reducing to a certain temperature to accelerate heating temperature, reaction time after cooling to produce the necessary powder iron phosphate lithium Sony VGP-BPL8 Sony VGP-BPL8A. Our core technology is the use of mixed ion doping process (Fig. 1) and liquid carbon coated technology. Lithium iron phosphate through the iron fence put up little silicon, the introduction of oxygen potential of fluorine, chlorine, sulfur and other elements doped, resulting in a lithium-ion Holidays, substantial increase in the conductivity of iron phosphate bulk lithium ion, one stroke solve the iron phosphate lithium large magnification poor performance, poor low temperature performance gaps.

 

With “liquid carbon coating” process, effectively improve the distribution of particle surface morphology LiFePO4 and carbon, has considerably improved the electronic conductivity of LiFePO4 and achieve its nano-particle technology.

 

Get this powder process of lithium iron phosphate has the following structural parameters: D10 0.8μm; D50 2.00 ~ 3.00μm; D90 20μm; tap density of 0.8 ~ 1.0 g/cm3 and that the area of 18 ~ 20 m2 / g, the morphology of micro-enterprises, see electron microscopy. Showed a spherical particle, the particle size of 200 ~ 500nm, the second spherical particles, dispersion, excellent with an average particle size of about 2 ~ 3μm. Vostro 1500 battery Vostro 1700 battery

 

As the electronic conductivity of lithium iron phosphate and ionic conductivity have been greatly improved, so the battery displayed an excellent performance. 2032-half of such cells, 0.2C on the following capacity to 145mAh / g, 0.2 ~ 10C under the voltage drop of only 0.25 V, the capacity fell only 25mAh / g , 10C, 300 cycles, the retention capacity was 95%;

 

Phosphate LiFePO4 cathode material, among others, Li3V2 (PO4) 3 is also good for security and electrochemical properties are also ideal, is to become the EV and HEV Li-material ion battery cathode. Li3V2 (PO4) 3 with monoclinic structure, and its relatively high ionic conductivity compared to LiFePO4, but its electronic conductivity is still low, usually through carbon coated to improve its electronic conductivity. We are prepared using solid phase reaction of carbon coated Li3V2 (PO4) 3, respectively, and citric acid (citric acid), sugar (glucose), polyvinylidene fluoride (PVDF) and starch (starch ) as the pyrolytic carbon reduction after the agent, excessive carbon may also act as agent driver. Finally found that the use of citric acid powder obtained has a high capacity to 3.0-4.3V at 0.2C charge and discharge, the availability of 118mAh / g reversible capacity, and not after 100 cycles the capacity decay, obtained from the PVDF powder magnification excellent performance in the discharge 5C under magnification will always be able to reach 95mAg / h capacity. PA3399U-2BRS PA3465U-1BRS

 

3 high anode material securities – the materials anodic oxide metal

 

Calorimetry studies have shown that metal oxides such as Li4Ti5O12, Fe2O3, so that the graphite anode shows better thermal performance security. Li4Ti5O12 because of the good structural stability known as the zero material strain, high load and platform discharge (1.5 V vs. Li + / Li) to match the thermal reaction of the electrolyte compared to the reaction Lithium intercalation of graphite with the electrolyte from the heat much more relaxed, and can reduce the transport of ions through nano-based way to improve the performance of battery power, so this material also showed the power of Battery broad application prospects, is expected for high density power system battery.

 

By thermal polymerization of acrylic acid were prepared nano-powders Li4Ti5O12, the powder sintered at 750oC average particle size of 120 nm, good performance of the electrochemical properties of the loop 100 times, the reversible capacity is still as high as 160 mAh / g, but also in the 10C Under the flow can reach 122 mAh / g capacity. IBM ThinkPad T42 battery  IBM ThinkPad T43 battery

 

To facilitate industrialization, we have also been achieved using solid-phase synthesis of Li4Ti5O12, due to lack of access to the nanoscale solid phase method of powder to obtain a magnification of good performance, we use the name of the composition of Cu-doping to prepare Li4Ti5CuxO12 powder X +, and get the best composition of x = 0.15 when the powder Li4Ti5Cu0.15O12.15, this material contains two types of structure spinel, namely Li4Ti5O12 and Li2CuTi3O8 first lithium intercalation process, Li2CuTi3O8 through the following reactions produce the same quality of Cu, Cu resulting uniformly distributed in the electrode, the electrode significantly increased the electronic conductivity, thus improving performance of battery power.

 

Li2CuTi3O8 + 2 Li = 0.6 Li4Ti5O12 + Cu + 0.8Li2O

Nano metal oxide transition as anode materials for lithium-ion batteries can significantly improve the battery charge or discharge capacity and performance of the new generation of lithium-development of ion battery in a direction important, with good development prospects. We have developed a simple synthetic method and practice – the heat curing acrylic, and particle size were prepared using this method, homogeneous and nano-Fe2O3 nano-composite Fe-oxides Li By optimizing the precursor liquid formulations, the calcination temperature, electrode formulation and so on, we have prepared a good electrochemical performance of nano-Fe2O3-based anode for lithium-ion G5266 HD438 battery after 200 cycles, the electrodes were able to meet that capacity 1300mAh / g or more. And we use it for industrial batteries, through testing short-circuit the negative than the usual graphite anode has a better safety performance.

 

4 The high-security system of the electrolyte

 

Electrolyte contains high activity of flammable organic solvents led to lithium-security issues of Ion battery is an important reason, developing the electrolyte of high security, to solve its security problems are the most direct and effective. As of dimethyl methylphosphonate (DMMP) has a higher than the TMP and other phosphorus content of phosphate, should be more efficient flame retardant, DMMP high viscosity and low dielectric constant possible to ensure that the electrolyte electrochemical performance is not affected, while the low freezing point most likely to improve properties of existing low temperature electrolyte, in addition to the price advantage DMMP widely used to increase their weight.

 

. This electrolyte at low temperatures showed more than usual electrolyte (1M LiPF6/EC + DEC (1:1 wt.)) A higher conductivity in the cathode half cell LiCoO2/Li established a greater discharge capacity and better performance at low temperature. PP2182L HSTNN-LB31

 

DMMP compatibility problems even though it may be, and, like many other additives, it is extremely difficult, and graphite negative, but more effective flame retardant in reducing the amount of fire retardant characteristics to facilitate the contradiction between the graphite-compatible and can be adopted (1) The use of modified graphite surface, (2) and forming compound additive are two ways to resolve this contradiction. By adding 5% of film forming electrolyte additives, vinyl ethylene carbonate (VEC), the electrolyte and the spherical MCMB graphite and amorphous carbon-coated graphite (SMG) of the compatibility between the marked improvement in LiCoO2 / MCMB and LiCoO 2 / SMG best performance throughout the performance of the cell cycle, LiCoO2 / SMG full battery in the loop 50 times, the capacity retention rate of 82% or more.

 

Structural stability of the anode and the DMMP-based electrolyte Li4Ti5O12 there is greater stability, we Li4Ti5O12 the LiNi0.5Mn1.5O4 with 5V cathode material with the formation of a new 3V battery, using the aforementioned high DMMP security based on the electrolyte in the absence Canadian film-forming additives which may be more compatible with the positive and negative electrodes, and demonstrated throughout the cell may be comparable to the performance of conventional battery electrolyte, which for High security in the use of the anode electrolyte lithium titanate power the field of batteries and battery energy storage to display a broad application prospects. PA3383U-1BRS PA3395U-1BRS

 

5 Conclusion

 

Lithium-ion batteries high security depends on the use of materials of high security. LiFePO4 and Li3V2 (PO4) 3 phosphate cathode material has an excellent safety, we have prepared by solid-phase powder has a good battery performance, especially with the performance of outstanding magnification is scheduled for the next generation of access to power battery applications. Materials of metal oxides as the anode in existing graphite anode showed better security, we have synthesized by thermal polymerization of nano-materials magnification Li4Ti5O12 anode has excellent performance, while solid phase prepared by Li4Ti5CuxO12 + x powders, because of the original Cu single bit of build quality, improve significantly the conductivity of the electrode, and substantially increase the performance of battery power; Fe2O3 nano-and nano-Li-Fe composite oxide as anode material is a class of high capacity and safety of cathode materials with wide application prospects. High security against the use of electrolyte materials, lithium-ion battery safety of the most cost effective manner, DMMP-based electrolyte has an excellent safety and conventional LiCoO2 / C system and a new battery LiNi0.5Mn1.5O4/Li4Ti5O12 Battery Systems showed good performance of the battery, such M8403 A1079 battery electrolyte in the industry is expected to quickly gain access.

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Urgent need for both internal and external charging

Posted by admin on January 21, 2010
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Accelerate technological upgrading and product updates, held in Beijing recently loudest voices of the Ninth China International Battery Fair. Experts say some Chinese still need to improve product quality, VGP-BPS2A VGP-BPS9A batteries need to upgrade industrial technology, the electric vehicle batteries, zinc-manganese batteries urgent need to adjust the product structure.

 

The experts also said, my batteries are very dependent on international markets, particularly in solar cells, more than 95% of exports, 90% dependent on imported raw materials, “two thirds” Market risk is too high but have also created nonprofit industry-shifting. Relatively backward industrial base of raw materials, key materials still rely on imports, high energy consumption of China and the high pollution in exchange for only a very low cost effectiveness. Such as manufacturers of solar cells, the average profit margin is only 8% if the deduction of tax rebates on exports, the core business unprofitable.

 

Battery Industry is an overall advantage of traditional industries, but with new materials, new processes, new technological developments, the battery industry is increasingly one of the emerging industries in high technology. According to reports, in recent years the development of the battery industry, China has shown the following characteristics: production has steadily improved, the rapid export growth, technological progress, accelerated product structure more reasonable, diversified companies, the large-scale development, and equipment levels gradually increased, overall strength improved markedly. Battery industry has also led to the development of electronics in China, not non-ferrous metals, chemicals, mining, machinery and other related industries, construction in the national economy has played an important role. IBM ThinkPad R32 battery  IBM ThinkPad R50 battery

 

The survey showed that nearly five years, sales of batteries from China more than 20% rate of annual growth rate of output growth of about 10%, well above the world average. In the past, my batteries low in the main traditional products now mercury-free alkaline manganese batteries, lithium batteries, sealed maintenance-free valve-regulated lead acid batteries, solar cells Dengjun experienced rapid development. That industrial restructuring in the world in recent years, China is developing in the global battery production, processing and commercial center, is the world’s leading producer of batteries.

 

However, by the international financial crisis since the second half of 2008, China’s commercial battery industry growth rate of exports has continued to decline, sales of batteries accounts receivable to increase, the economic decline . While mobile phones, cars, electrical bicycle battery accessories such as the contraction in output and sales volume, the growth rate of production of the battery decreases. Some staff members to participate in the show business of the company, now face the plight of battery cost increases are mainly caused by the less competitive market, corporate profits have fallen sharply. Dell Inspiron 1100 battery  Dell Inspiron 1150 battery

 

China Light Industry Information Center, according to parties involved in the first quarter, China’s battery industry as a whole race showed the following characteristics: Although the output of a recovery in manufacturing growth above battery designated output size of 9.87 percent over last year, but the international market, depressed the first quarter exports battery last year fell by 31.86 percent against. The toys affected by the export trade, the fourth button cell alkaline manganese exports continued to decline, the cylindrical cell alkaline manganese export volume decreased slightly, other alkaline manganese batteries to accelerate the decline of exports. At the same time, business costs, lower profits. 1 ~ 2 months of this year, the battery industry, these enterprise-wide total profit fell 68.78 percent, the battery industry, these enterprise-wide face a loss of about 31.19 %, total loss of 7.85 billion yuan, compared with losses last year rose 215.78%. And the expansion of trade deficits, corporate operational difficulties. Effects of tax adjustment of China’s export rebate policy is not yet clear, but the green barriers abroad, the impact of the battery industry in China continues. According to the Official Journal of the EU “directives issued by the batteries, batteries lead, cadmium, mercury objective fact, more demanding and requires commitment fees for cost recovery. REACH Regulations and guidelines to improve the registration fee of battery charge and ROSH test, the substantial increase in cost of battery production and marketing costs for export, some companies have been for economic reasons and technical reasons, to abandon foreign markets. hp Pavilion dv2000 battery  hp Pavilion dv6000 battery

 

Currently, the battery industry in China is facing an industrial upgrading overall. China Battery Industry Association, said the Secretary-General Wang Jingzhong, recently adopted the “restructuring of light industry and the revitalization of the planning will contribute to the restructuring of the battery industry and industrial modernization. The battery industry should take this as an opportunity to work for the localization of technical equipment to make significant progress and has formed a group with strong international competitiveness of key enterprises, so that the national product and market development The value added of exports significantly improved, more diverse marketplace. While promoting the largest producer of electric vehicles, power tools power from the battery to form a new industrial scale, making China the world of rechargeable batteries, the solar cell production to maintain the global leader and accelerate market development and gradually alleviate the shortage and the variety of low battery increase exports, improve product quality and value. “Strengthening the internal force is the key.” Jingzhong Wang said. PA3383U-1BRS PA3395U-1BRS

 

According to reports, the next few years, the Chinese battery industry will accelerate the technological upgrading and product upgrades to improve effectively the risks of industry resistance capacity and international competitiveness, and strengthen the capacity of independent innovation and strengthening the brand, a perfect business system to support innovation, and the subsequent implementation of the technology and equipment domestic production, diversifying markets for accelerate industrial battery manufacturing power in the world in a global manufacturing power forward. Physics, Chinese Academy of Sciences, experts said the creation of the National Research Center for the battery industry, the integration of the industry to improve the capacity of independent innovation, promote the industry, technological advances, we should focus on progress in electric vehicles, vehicle batteries and battery materials, key technologies and key research and industrialization. Chinese market for electric bicycles to developing lithium-ion battery industry has provided opportunities. “Electric vehicle battery is the most critical components, but also brings together multi-disciplinary results of scientific research, companies need the government to focus on a selection of high quality support.” In the exhibition, many companies made such a request. M8403 A1079

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