1 Introduction
With the power supply and distribution, communications, industry, telecommunications and development of electric vehicles, has also led to its full power – industrial development of the battery and technological progress and innovation. As the lead-acid F3172A PB995A 338794-001 battery in a cost-effective, so that the current domestic market and abroad, and more portable electronic devices for electric vehicles, UPS systems, telecommunications (telecommunications centers, earth stations) , diesel, automotive powerhouse, substation, emergency power, shipping and light areas without electricity projects such as energy supply energy storage is used by over 95% of lead-acid batteries. Lead acid batteries in 2005 was 66.45 million KVA output, total output value of 350 billion yuan, total production in 2006 totaled 84.57 million KVA, with a total of 420 billion yuan or one third of the value of the total production of the battery industry left and right (data from the two power board in Jiangsu Corporation consultants Jingming Dai).
Different models, different environmental conditions using the battery life of design is also different. As determined battery exhaust lead-acid at 20 ℃ ~ 25 ℃, under the floating charge to use the life expectancy of 15 years VRLA lead acid batteries used in a load of floating of his life in 5-10 years; traction type (dynamic type) exhaust the life of lead-acid 361742-001 371785-001 417066-001 battery is 1500 cycles, the type of power of the VRLA battery life lead-acid is 700 per cent electric bicycles, electric motorcycles, electric tricycles support for both lead-acid battery life of only about 350 weeks, or years, corresponding to the car ignition, lighting, start with the general life VRLA lead-acid battery is 3 to 5 years, so the repair lead-acid market share in the farm to the bigger, the frequency of use, the most widely used, life expectancy was short and prone to early failure of lead-acid battery is the main object. Prone to early failure of these batteries may resubmit its use after the repair, so the extended life battery, an environmentally friendly energy saving purposes.
2, the main reason for premature failure of lead acid batteries
The main reason for premature failure of lead acid batteries is:
(1) of the lead-acid battery manufacturing their own quality and quality problems;
(2) and the corresponding lead-acid battery charging equipment (charger) to recharge the battery and the mode is not the problem; 346970-001 367759-001 F2024A
If the lead-acid battery charging and load (loader) does not match the high charging voltage charging time is too long will lead to electrolyte (sulfuric acid solution) in the accelerated decomposition of water to produce hydrogen, oxygen within the battery can be fully composite This accelerates water loss from the battery, and increased electrode corrosion, accelerated aging and premature aging of the emergence of batteries.
(3) users of lead-acid batteries can not use the maintenance requirements of the battery in accordance with the use and maintenance of batteries; F2024B F4486B F4809A
If excessive use of lead-acid battery will be discovered, a positive plate of lead dioxide particles in the degradation of the bridge driver, will lose some of the contacts between particles of lead dioxide and nitrogen dioxide and particles between network of contacts, which means the single particle is not involved in the electrochemical reaction, weaken the strength of the active substance, the possibility of falling increases. Excessive use (more discharge) would be negative active material in the loss of blowing agent because of the effects of oxidation and increase the irreversible formation of sulfate crystallization. Often, over-utilization (the exercise) will result in loss of activity of active substances premature conversion of active material during charging weakening, leading to accelerated capacity fading of lead acid batteries and emergence of early failure. F4812A HSTNN-lB31 PB991A
(4) Defeated, falling, collision damage caused by the plastic housing of the battery can cause very serious damage to the inner ear and the plate so that the battery is completely ineffective, a premature retirement.
3, the failure of the repair of lead-acid battery
Not all failures lead-acid battery can be repaired, such as the emergence of short-circuit and open the battery, a battery very serious off-board active material, plates were seriously damaged, severely deformed drums, plastic housing of the battery, a serious distortion and serious breaches of the battery and the plastic housing of the battery to drain down the battery of large surface can be repaired. Therefore, repair of lead-acid battery is a serious failure due to water loss, the active electrode material breach sulphate battery, as well as for repair, blows, falls and Other causes of upper battery shell cracks and leaks appear weak cause failure of the battery, that is, minor structural failure of the battery. Therefore, repair of lead-acid battery can be divided on the failure of the electrical properties of the plastic housing, rehabilitation and repair of the failure of structural parts. acer Aspire 5920 battery acer Aspire 5520 battery
3.1 The failure of the repair of electrical properties of lead-acid battery
The failure of the electrical properties of the repair of lead-acid battery can be divided into physical and chemical methods of repair patch.
3.1.1 Non-chemically on the electrical properties of the repair of lead-acid battery [1]
Standard chemical properties of the electrical repair lead-acid battery is commonly used methods for attaching chemical activator, such as carbon nano battery soil activator, it is a nano-graphite main ingredients of the aqueous solution of solute. acer TravelMate 220 battery acer TravelMate 240 battery
3.1.1.1 Activation mechanism
Activator carbon nano-scale battery Sol is around 10-10 ~ 10-7 m nano-carbon (graphite), the main body and contains a variety of battery activation effectively ( as nano-silica), materials with high activity preparation of. As the carbon in the nanoscale range, have a large surface and high specific surface energy, it has many unusual properties, such as high chemical activity, catalytic activity, surface adsorption selective excellent conductivity and its negative charge. When the soil carbon nano-activator of the battery to the electrical properties of the internal failure of lead acid batteries, the electric field under the influence of nano-graphite is rapidly adsorbed on the electrode surface and higher penetration into the inner electrode. Adsorption on the active electrode material between the active substance which increases the bond strength between the two, and active matrix bond strength, can inhibit the excretion of active and active substances and sulfuric acid sulfate may have a passivation activity recovery of salt material. But also reduce the internal resistance of the battery, which increases the conductivity of the electrode, the electrode to improve and restore the functions of the electrode to increase the structural strength of the charging and discharging of the energy and chemical energy conversion between the improvement and strengthening support the improvement and efficiency of discharge of the battery capacity has been restored for repair. acer TravelMate 250 battery acer TravelMate 260 battery
3.1.1.2 Soil Activator Nano-carbon battery usage
(A) serious loss of water by adding an activator of lead-acid battery to the concentration before the first tranche of 5% to 10% sulfuric acid electrolyte, the addition of electrolyte concentration in liquid line between the upper and lower spot on the line.
(2) By addition of an activator required the use of plug holes in the air and even around the middle of each monomer added to the internal battery and stir regularly. Increased carbon nano activator Sol After almost liquid line liquid electrolyte on the line marked online.
(3) the immediate restoration of the battery, the charging current when charging began activation of the normal load current is greater than about 50%, so the role of nano-graphite in the earliest possible inside the adsorption to the electrode cover about 40% in again when the normal load of electricity. Activation of the capacity of the first theoretical capacity of 120% ~ 130%. acer TravelMate 280 battery acer TravelMate 290 battery
General activation of 2 ~ 3 weeks after the battery performance can be restored, the discharge capacity of the rated capacity of over 98% of the repair can be considered completed. Cell activation on the surface of the electrolyte after the repair of the large surplus of electrolyte to be drawn.
Activated before the battery into the battery electrolyte in trouble and brown, and if there are solid particles, but the discharge capacity of nearly 80% of the nominal capacity of the battery, the electrolyte must rinsed (or suction) and battery with pure water cleaning 2 times and then adding the concentration of sulfuric acid electrolyte used, the above method of activating the repair of the battery. acer TravelMate 3000 battery acer TravelMate 4000 battery